Is Blacephalon worth a Master Ball?

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Your call: leans yes

Ultra Beast. Ultra Beasts are raid bosses Niantic periodically re-runs, so missing one event doesn't mean missing it forever. It's a reasonable use of a Master Ball if you don't mind spending it.

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Species info

FireGhost

Attack315

Defense148

Stamina142

Notable moves: Incinerate, Astonish, Overheat, Shadow Ball, Mystical Fire