Is Lunatone worth a Master Ball?

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Probably not

Regional exclusive. It's not gone for good - just gated by geography rather than time, and solvable with a trip or a trade. You're probably better off saving the Master Ball for something rarer.

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Species info

RockPsychic

Attack178

Defense153

Stamina207

Notable moves: Rock Throw, Confusion, Psywave, Moonblast, Psychic, Rock Slide