Is Marshadow worth a Master Ball?

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No, save it

Mythical, but this is a guaranteed-catch encounter - Special Research rewards and similar can't flee and are caught on the first throw no matter what ball you use. A Master Ball buys you nothing here, so save it for an encounter where catching isn't already a sure thing.

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Species info

FightingGhost

Attack265

Defense190

Stamina207

Notable moves: Sucker Punch, Counter, Poison Jab, Shadow Claw, Close Combat, Rock Slide, Fire Punch