Is Metagross worth a Master Ball?

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Probably not

Pseudo-legendary. It's a strong non-Legendary with a full evolution line, not usually a limited encounter - though this varies by species; Dreepy in particular has a notoriously low spawn rate. You're probably better off saving the Master Ball for something rarer.

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Species info

SteelPsychic

Attack257

Defense228

Stamina190

Evolves from Metang.

Notable moves: Bullet Punch, Zen Headbutt, Fury Cutter, Earthquake, Flash Cannon, Psychic