Is Nihilego worth a Master Ball?

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Your call: leans yes

Ultra Beast. Ultra Beasts are raid bosses Niantic periodically re-runs, so missing one event doesn't mean missing it forever. It's a reasonable use of a Master Ball if you don't mind spending it.

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Species info

RockPoison

Attack249

Defense210

Stamina240

Notable moves: Acid, Pound, Poison Jab, Gunk Shot, Sludge Bomb, Power Gem