Is Poipole worth a Master Ball?

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Yes, worth it

Ultra Beast (one-time encounter). Unlike other Ultra Beasts, which Niantic periodically re-runs as raid bosses, this one has only been offered once - a Special Research reward with no confirmed second chance. This could be a candidate for a Master Ball.

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Species info

Poison

Attack145

Defense133

Stamina167

Evolves into Naganadel.

Notable moves: Poison Jab, Peck, Sludge Wave, Sludge Bomb, Fell Stinger