Is Raikou worth a Master Ball?

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Your call: leans yes

Legendary (frequent raid boss). Unlike most Legendaries, this one rotates back through raids often enough that missing it usually isn't your last shot. It's a reasonable use of a Master Ball if you don't mind spending it.

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Species info

Electric

Attack241

Defense195

Stamina207

Notable moves: Thunder Shock, Volt Switch, Thunder, Shadow Ball, Aura Sphere