Is Zacian worth a Master Ball?

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Your call: leans yes

Legendary (frequent raid boss). Unlike most Legendaries, this one rotates back through raids often enough that missing it usually isn't your last shot. It's a reasonable use of a Master Ball if you don't mind spending it.

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Species info

FairySteel

Attack254

Defense236

Stamina192

Notable moves: Metal Claw, Snarl, Quick Attack, Fire Fang, Close Combat, Play Rough, Wild Charge